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1 article(s) from Hermann, Sergej

Photocatalytic nucleophilic addition of alcohols to styrenes in Markovnikov and anti-Markovnikov orientation

Martin Weiser,
Sergej Hermann,
Alexander Penner and
Hans-Achim Wagenknecht

Beilstein J. Org. Chem. 2015, 11, 568–575, doi:10.3762/bjoc.11.62

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Graphical Abstract

Scheme 1: Photooxidation of the substrate and reductive quenching of the photocatalyst (left) vs photoreducti...

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Scheme 2: Mechanism of the Markovnikov-type photocatalytic addition of methanol to 1,1-diphenylethylene (1) a...

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Scheme 3: Intramolecular photocatalytic addition with substrate 3; reaction conditions: 3 (2 mM), Py (2 mM), ...

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Scheme 4: Proposed mechanism of the anti-Markovnikov-type photocatalytic addition of methanol to 1,1-diphenyl...

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Figure 1: Conversion of substrate 1 and formation of product 5 observed during photocatalysis with PDI in the...

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Figure 2: Conversion of substrate 1 (black dashed) and formation of product 5 (red solid) observed during pho...

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Figure 3: Spectra of PDI before (dotted black) and after excitation (red), then every 2 min until ground stat...

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Scheme 5: Intramolecular additions of substrates 8 and 10 to demonstrate the effect of different electron den...

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Published 27 Apr 2015

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